I able to reproduce your behavior. But, when I switched to using ai0 as the trigger source, I could not. Always triggered from the falling edge with hysteresis of 0.2.
Perhaps such a high value of hysteresis is needed for stable triggering when PFI 0 is used because the comparator in this circuit has only 8 bits of resolution. Plus, this circuit has a fixed range of 20V (+/- 10). This gives a resolution of only 75mV. When you use ai0 as your trigger source, you use the 12 bit ADC of the device as well as its gain stage. But, to use ai0 as a reference trigger source, it must be the only channel in your task.