The voltages read by the software (not LabView) were higher (6-9V) to those I read with a voltmeter (0.57 V)
Is your software configured to read that particular channel, in the same mode as it is connected?? check it out
Also check voltage reading on that channel using MAX test panel after selecting the appropriate mode. Now, see if your values match with your voltmeter reading
This will confirm that your wiring is correct and its the software that is intepreting the ADC reading incorrectly
Regards,
Dev