Open the example finder (Help>>Find Examples) and look at the Write Datalog File example. You can also convert your data to text to save a simple text file. Also, the tutorials in the following links probably cover something similar.
To learn more about LabVIEW, I suggest you try searching this site and google for LabVIEW tutorials. Here, here, here, here and here are a few you can start with and here are some tutorial videos. You can also contact your local NI office and join one of their courses.
In addition, I suggest you read the LabVIEW style guide and the LabVIEW user manual (Help>>Search the LabVIEW Bookshelf).
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