Don't use the RS232 port. By design, it will send out a start bit, 7 or 8 data bits, and stop bit(s). You cannot change that. Therefore it is not ideal for sending out pulses of certain duration. Instead use the parallel port. Labview has examples on how to use the parallel port. You can also search NI website for examples. Just set one of the lines high, wait for 1msec, then set it low.