The USB 6009 has digital outputs, so do you actually *have* to use the analog output channels?
If so, there are generally 2 ways to do this:
Method 1: Write out a single value (4V), wait, and then write out a 0.
Method 2: Create a waveform that's your pulse, and write out the waveform.
Unfortunately, the USB 6009 is a software-timed device as it has no onboard memory, so you can't use Method 2. You can find examples that ship with LabVIEW on analog output generation (Help -> Find Examples). You can also just use the DAQ Assistant.