I dont know if there is a way to generate this Trigger signal directly from the hardware (either from PXI-4472B or from PCI-6036E). Now if you choose to give the responsibility of generating Trigger signal to software (your LabVIEW program commands PCI-6063E to generate Trigger signal, based on whatever condition), that can be done, but I am afraid, this will not be deterministic.
Now there are many different options available to write a code for above requirement.
1. You can include a LV2G (Functional global) with 'Creating Task', 'Generating Pulse', 'Clearing Task' modes. Keep this LV2G in the accelerometer acquisition loop and everytime based on the condition you may want to execute this LV2G.
2. Another approach could be, include a parallel loop, which will continuously monitor the condition and will generate the signal.
To generate the digital trigger:
1. You can choose to write a waveform (need to create a digital waveform constant).
2. You can also simply choose to use Digital write.
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