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I looked at the Devzone about the Desktop PC Hardware Requirements and it states that the problem has to do with size and the type. I have added the paragraph that deals with this issue below:
All LabVIEW Real-Time versions support Parallel ATA in IDE while LabVIEW 8.5 (and above) and LabWindows/CVI RT 8.5 (and above) support Serial ATA only in AHCI. LabVIEW Real-Time and LabWindows/CVI RT versions prior to 8.5 do not support Serial ATA. LabVIEW Real-Time 8.6.1 and previous supports hard drives up to 126 GiB. LabVIEW Real-Time 2009 and above support hard drives up to 1.99 TiB. The following options may be available depending on the specific desktop PC.
Jim St National Instruments RF Product Support Engineer