Dan,
Absolutely, the NI-TIO chip on the PCI-6602 supports a start trigger. If you configure all of the counters that are generating a pulse train to use this start trigger, they will be synchronized. The example Generate Pulse Train - Start Trig (NI-TIO).vi demonstrates this process for one counter. In LabVIEW 7, this example can be found in the following location:
Examples >> Hardware Input and Output >> Traditional DAQ >> Counters >> NI-TIO
You will need to add code for the other counters, but this example should give you the general idea. Furthermore, this example demonstrates how you can use one of the digital lines to generate the start trigger.
Good luck with your application.
Spencer S.