Adriano,
Since I am not an expert in VB programming, I am just guessing a little here. Does your VB DLL use any other VB DLLs? I am guessing that since LabVIEW can see the methods and properties, everything is correct from our side, but when the VB DLL calls something internally, it is not found and the error is propagating upwards.
Randy Hoskin
Applications Engineer
National Instruments
http://www.ni.com/ask