First, you need to know the format in which your pH probe sends data over Bluetooth.
LabVIEW comes with a Bluetooth palette, you could leverage it,
Next, your Syringe Pump has an RS232 port, you can connect it to the computer using a USB-RS232 cable, check if they supply any LabVIEW driver, if not, once you understand the commands you need to use, you can develop your own driver - this is a good article to understand VISA communication https://labviewwiki.org/wiki/VIWeek_2020/Proper_way_to_communicate_over_serial