I have a couple of things for you to try.
First, place a "VISA Resource Name" I/O node on the front panel of a
blank VI. Does the alias for your instrument show up in the drop
down menu? If so, can you use a VISA read and VISA write to talk
to the instrument? This will help isolate whether the problem is
with VISA in LabVIEW or with the IIOA.
You can also try following the instructions in
KnowledgeBase 3JND42HY: "Instrument I/O Assistant Not Installed Properly" Error to reinstall the IIOA.
What version of NI-VISA do you have installed? As the KB recommends, you can try upgrading to the latest version, 3.5.
Robert Mortensen
Software Engineer
National Instruments