I did some further research and found the following document:
http://digital.ni.com/public.nsf/websearch/914D96F95777CBDF86256C05007774C0?OpenDocument
Also, our DSA products are not intended to be used in applications where DC accuracy is important. DSA is good for linearity, alias rejection, and dynamic range. When looking at accuracy there are 2 important #'s on the 4472: Amplitude Accuracy (+/- 0.1dB) and Flatness (+/-0.03dB). 0.1dB corresponds to about 1.0% error so if you have a calibrator generating a 5.0000V signal, we guarantee that you will see between 4.95V and 5.05V. Now this does not seem very good, but "absolute amplitude accuracy" is not the most important spec for this type of device. The 4472 employs extreme linear ADC's, this means that the error seen across all the channels is going to be the same. So if you are measuring a 5.00000V signal and you actually see 5.1V then you can be assured you are going to see 5.1V on all the channels. Another way of expressing this error is linear Gain and this inaccuracy is typically accounted for in a system-level calibration before you start taking measurements.
Let me know if this offers you any help and have a great day!
Bryan Snarr
Field Engineer
Northern California
National Instruments