Hi JPD,
Unfortunately, there is no way to improve the resolution and remove the "stairway" effect on the PCI-6025E board without external circuitry. This means you would have to use an attenuator external to the board and output your signal with a higher gain to compensate for the external attenuation.
Many of the other E-Series boards do support a couple things to improve the stairway effect, including having a board with higher output resolution.
The best way to maximize your resolution without external circuitry is to use an external reference for your DAC. The board itself uses an internal reference that you can set up to be either +/-10 Volts or 0 to 10 Volts. If your signal fits well within this range, then this reference works fine. If your sig
nal range is much smaller than this range, then your resolution may not be very good. This is important because cutting your range in half improves your resolution by a factor of 2. You can use the pin "EXTREF" (check your manual to see if the board supports this) to connect your own voltage reference. The DAC will use this range to convert your signal from Digital to Analog. Effectively what you are doing is changing the range of your DAC to fit the range of your signal. In the analog input case, you are changing the range of your signal to fit the range of your ADC. Same concept...different implementation.
Anyway, I hope that helps.
Ron