You were right, my modules were placed on the 1 and 2 slots, so I switched them to the 5 and 6, but it still didn't work. I tried to open the file you attached, but an error comes up saying that the file is of a newer LabView version (8.5, I've got 8.0). I looked on the example finder and found one that does simultaneous AI and AO (does it programmatically), but that one didn't work saying:
"Error -89136 occurred at DAQmx Write (Analog Wfm 1Chan NSamp).vi:1
Possible reason(s):
Specified route cannot be satisfied, because the hardware does not support it.
Property: SampClk.Src
Property: SampClk.ActiveEdge
Source Device: cDAQ1Mod6
Source Terminal: ai/SampleClock
Task Name: _unnamedTask<0>"
Now I am really confused! I thought this hardware DID support it... I tried rebooting, swapping 5 and 6, then rebooting again. I've tested each device and they seem to be doing AI and AO just fine, but without trigger. Also, after I switched them to 5 and 6, the trigger options were still grayed out.