Robin,
I would recommend using Pattern Generation Output on the 653x (DIO-32HS) board. Then set the DIG_Block_PG_Config function call to look for an external clock for output operations.
You would set up the output port to a 32-bit port and connect the external clock to the REQ 1 pin of the 653x device.
Examples for doing Pattern Generation in VB can be installed through the NI-DAQ driver when you choose to install support for VB.