Zhichao;
There are some things you will need to be concerned about when performing such task.
First, you need to make sure the polarity of the ACK and REQ lines of the 6534 are set to active low (as the OBF and ACK lines at the DIO-96 are active low).
Second, if you are using the Dig Buf Handshaking.vi example, and let the group to be 0, then you will need to use ACKA and OBFA instead of ACKB and OBFB.
Last thing you need to set correctly is the handshaking protocol at the 6534. You can also set a programable delay at the 6534 (see User Manual), in case the DIO-96 is not able to keep up how fast the ACK and REQ lines change at the 6534 board.
Hope this helps.
Filipe