It's enough for you to calculate the timestamp based on the starting time and on the actual scan rate?
If so, you can use Actual Scan Rate output by AI Start.vi to calculate the timestamp array: simply accumulate the inverse of it over for example the value obtained by Get Date/Time in Seconds.vi.
Look at Get Waveform Time Array.vi to learn how NI calculates the timestamp array in Export Waveform To Spreadsheet.
That way you are uncertain of the initial value due to the unpredictability of Windows, but from that moments on the progression is regular and reflects the actual work done by the acquisition card.
Roberto