The NI-DAQ function call Set_DAQ_Device_Info changes the data transfer mode (interrupts and DMA) for certain classes of data acquisition operations (including buffered transfer for the PCI-DIO-32HS). Use the NI-DAQ Function Reference Manual (linked below) as a reference.
NI-DAQ Function Reference Manual
http://digital.ni.com/manuals.nsf/webAdvsearch/47EB30B6651A0F4D8625665E0063589D?OpenDocument&vid=niwc&node=132100_US
Regards,
Todd D.