Hi,
I belive Bilal is right, bioscom() is not a CVI or ANSI C function; you may want to consider CVI's built in libraries for serial communication. There are a bunch of examples on that and if you have CVI 7.0 you can use the Instrument IO assistant that can help you generate code for the communication and parsing.
You can find some example on serial communication at:
C:\Program Files\National Instruments\CVI70\samples\rs232
or you can to http://www.ni.com/examples select CVI and serach for serial.
I hope this helps!
Regards,
Juan Carlos
N.I.