To fit the data, you need the correct model. What kind of function are you trying to fit? LabVIEW has a large collection of fitting tools. Do you have some example data?
To display multiple plots on the same waveform graph, the techniqe depends on the type of data.
If one plot is a 1D array, you would make multiple plots on the same graph by using "built array" and forming a 2D array.
If one plot is a waveform, use "built array" to make a 1D arra of waveform.
If you have dynamic data, use "merge signals" before feeding it to the graph terminal.