I just tried the IVI driver with my 33120A. I configured the instrument to use serial, 9600 baud, 8 bits, no parity. I used LabVIEW 6.1.
I loaded the Getting Started VI, and had to right click on the "resource name" and select "Allow Undefined Names". Then I could enter "COM1" (or "ASRL1::INSTR") and the VI ran.
I did run into a problem where the default amplitude (of 0.1 volts) is out of range, but if I change that to 1 volt, the VI runs with no errors.
If you are trying the serial examples, remember that most instruments require that you terminate your commands with a carriage return or linefeed (or both). Otherwise, your instrument will just ignore you. So, hit "enter" after you type "*IDN?" into your string. (You can turn on
"\ code display" by right clicking on the string if you want to enter or see \r and \n.)
I hope this helps.
Brian