Hi Richard,
The EtherCAT protocol normally operates on 100BASE-TX, and can also operate on 100BASE-FX (Sources here and here). I'm guessing you've seen the KB that explains you need different swtiches / hubs for EtherCAT and that has made you wonder if optical converters fall into that same category?
The need for special switches/hubs is because EtherCAT star junctions work differently than normal Ethernet hubs as the packets need a particular routing. However, optical converters are inline and do not affect the direction packets go. They are just converting bits from voltages to light pulses. The main thing to consider would be how much latency the converters introduce to the network - as this will end up influencing your minimum EtherCAT cycle period.
Having said all that, NI does not test optical converters, but I have heard of customers using optical converters before (sorry, no public-facing reference link available). As I mentioned above, the EtherCAT protocol does specificy 100BASE-TX and 100BASE-FX, so I would make sure the converter complies with those standards.
Andrew T.
"His job is to shed light, and not to master" - Robert Hunter