Hi Chang,
PCI-DIO-96 is a static DIO device and it is the recommended device for I2C Applications. You would need a correlated digital I/O for I2C Applications. In other words, you need board which can precisely correlate data bits with clock.
I would recommend using USB-8451. It has High-level, easy-to-use LabVIEW API. It can act as I2C master interface with clock rates up to 250 kHz which is well with in the range of LTC1867 rate. This would make your programming and interfacing very easy.
For further information, please refer to the following product page.
https://www.ni.com/en-us/support/model.usb-8451.html
Hope this helps.
Have a great day!
Kalyan
Kalyanramu Vemishetty
Automated Test Systems Engineer
National Instruments