Hey Scottw,
Stopping and starting the specific objects currently is not supported by the NI-CAN driver. If you use Transmit Data Periodically you can write data when you want and there is no need to stop the object or interface in most cases.
You can try to Close the object, and then use Config and Open to start writing again, but I can not guarantee it will work, because it is currently not supported.
We are looking into adding these feature in the future. If you have any input or suggestions on adding these features to the driver I would appreciate your feedback from our official product feedback forum.
http://sine.ni.com/apps/we/nicc.call_me?p_action=country&p_lang_id=US
JoshuaP
National Instruments